Tetrakis(μ-phenoxyacetato-κ2 O:O′)bis[(1,10-phenanthroline-κ2 N,N′)manganese(II)] methanol hemisolvate
نویسندگان
چکیده
The title complex, [Mn(2)(C(8)H(7)O(3))(4)(C(12)H(8)N(2))(2)]·0.5CH(3)OH, is a carboxyl-ate-bridged dinuclear Mn(II) complex with four phenoxy-acetate ions and two 1,10-phenanthroline mol-ecules as ligands. Each of the four phenoxy-acetate anions bridges the pair of Mn atoms. The asymmetric unit is completed by a half-occupancy methanol solvent mol-ecule. Face-to-face π-π stacking inter-actions between the aromatic rings of 1,10-phenanthroline molecules belonging to adjacent Mn(2) complexes, with an inter-planar separation of circa 3.4 Å, and weak C-H⋯O hydrogen bonds connect the dinuclear units into a three-dimensional supra-molecular framework.
منابع مشابه
Tetrakis(μ2-2-phenoxypropionato)-κ3 O,O′:O′;κ3 O:O,O′;κ4 O:O′-bis[(1,10-phenanthroline-κ2 N,N′)(2-phenoxypropionato-κ2 O,O′)cerium(III)]
In the centrosymmetric binuclear title complex, [Ce(2)(C(9)H(9)O(3))(6)(C(12)H(8)N(2))(2)], the two Ce(III) ions are linked by four 2-phen-oxy-propionate groups in bi- and tridentate bridging modes. Each Ce(III) ion is nine-coordinated by one 1,10-phenanthroline mol-ecule, two O atoms from a chelating carboxyl-ate, two O atoms derived from a μ(3)-carboxylate and two O atoms derived from two μ(2...
متن کاملcatena-Poly[[(1,10-phenanthroline-κ2 N,N′)praseodymium(III)]-di-μ-phenoxyacetato-κ4 O:O′-[(1,10-phenanthroline-κ2 N,N′)praseodymium(III)]-di-μ-phenoxyacetato-κ4 O:O′-di-μ-phenoxyacetato-κ3 O,O′:O;κ3 O:O,O′]
The title complex, [Pr(2)(C(8)H(7)O(3))(6)(C(12)H(8)N(2))(2)](n), which has an inversion centre midway between the two Pr(III) atoms of the structural unit, forms a one-dimensional polymer bridged alternately by either two bidentate, or two bidentate and two terdentate, phenoxy-acetate carboxyl-ate groups. Each Pr(III) atom is thus nine-coordinated by two N atoms of a 1,10-phenanthroline ligand...
متن کاملTetrakis(μ-2-phenoxypropionato)-κ3 O,O′:O′;κ3 O:O,O′,κ4 O:O′-bis[(1,10-phenanthroline-κ2 N,N′)(2-phenoxypropionato-κ2 O,O′)praseodymium(III)]
In the centrosymmetric binuclear title complex, [Pr(2)(C(9)H(9)O(3))(6)(C(12)H(8)N(2))(2)], the two Pr(III) ions are linked by four 2-phen-oxy-propionate (L) groups through their bi- and tridentate bridging modes. Each Pr(III) ion is nine-coordinated by one 1,10-phenanthroline mol-ecule, one bidentate carboxyl-ate group and four bridging carboxyl-ate groups in a distorted PrN(2)O(7) monocapped ...
متن کاملTetrakis(μ-2-phenoxypropionato)-κ3 O,O′:O′;κ3 O:O,O′,κ4 O:O′-bis[(1,10-phenanthroline-κ2 N,N′)(2-phenoxypropionato-κ2 O,O′)dysprosium(III)]
In the centrosymmetric binuclear title complex, [Dy(2)(C(9)H(9)O(3))(6)(C(12)H(8)N(2))(2)], the two Dy(III) ions are linked by four 2-phen-oxy-propionate (L) groups through their bi- and tridentate bridging modes. Each Dy(III) ion is nine-coordinated by one 1,10-phenanthroline mol-ecule, one bidentate carboxyl-ate group and four bridging carboxyl-ate groups in a distorted DyN(2)O(7) monocapped ...
متن کاملTetrakis(μ-2-phenoxypropionato)-κ3 O,O′:O′;κ3 O:O,O′;κ4 O:O′-bis[(1,10-phenanthroline-κ2 N,N′)(2-phenoxypropionato-κ2 O,O′)terbium(III)]
In the centrosymmetric binuclear title complex, [Tb(2)(C(9)H(9)O(3))(6)(C(12)H(8)N(2))(2)], the two Tb(III) ions are linked by four 2-phen-oxy-propionate (L) groups through their bi- and tridentate bridging modes. Each Tb(III) ion is nine-coordinated by one 1,10-phenanthroline mol-ecule, one bidentate carboxyl-ate group and four bridging carboxyl-ate groups in a distorted TbN(2)O(7) monocapped ...
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